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81.
Nikolay V. Kobernik Roman S. Mikheev Nikolay P. Aleshin 《Fullerenes, Nanotubes and Carbon Nanostructures》2020,28(7):515-520
AbstractDue to their high antifriction characteristics, the Sn-Sb-Cu alloys (referred to as babbits) are widely used to coat sliding bearings. However, some limitations of the present techniques for applying such coating materials cause a decrease in their fatigue strength because of the reinforcing phase particles growth. As a technique for restricting the increasing of the reinforcing particle sizes, this paper proposes plasma surface cladding with multiwall carbon nanotubes (MWNTs) as modifiers. The dry sliding friction tests performed according to the “pin-on-disk” scheme using as a counterface a steel 100Cr6 (DIN 17230) disk have shown that adding to the coating 0.25%wt of CNTs significantly improves the friction stability (the coefficient of friction process stability decreases twice with reducing the friction coefficient and wear resistance by 5% on the average). An attempt to reveal the mechanism for the MWNT influence on the structure and performance of the babbit-based coatings was undertaken. Studies of the coatings metal structure by soft X-ray absorption spectroscopy and also by the metallographic and fractographic analysis involving electron-microscopy have shown that MWNTs remain stable during plasma cladding process and save into the coating. 相似文献
82.
Guihua Liu Dan Luo Rui Gao Yongfeng Hu Aiping Yu Zhongwei Chen 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(37)
The practical application of lithium–sulfur (Li–S) batteries is hindered by the “shuttle” of lithium polysulfides (LiPS) and sluggish Li–S kinetics issues. Herein, a synergistic strategy combining mesoporous architecture design and defect engineering is proposed to synthesize multifunctional defective 3D ordered mesoporous cobalt sulfide (3DOM N‐Co9S8?x) to address the shuttling and sluggish reaction kinetics of polysulfide in Li–S batteries. The unique 3DOM design provides abundant voids for sulfur storage and enlarged active interfaces that reduce electron/ion diffusion pathways. Meanwhile, X‐ray absorption spectroscopy shows that the surface defect engineering tunes the CoS4 tetrahedra to CoS6 octahedra on Co9S8, endowing abundance of S vacancies on the Co9S8 octahedral sites. The ever‐increasing S vacancies over the course of electrochemical process further promotes the chemical trapping of LiPS and its conversion kinetics, rendering fast and durable Li–S chemistry. Benefiting from these features, the as‐developed 3DOM N‐Co9S8?x/S cathode delivers high areal capacity, superb rate capability, and excellent cyclic stability with ultralow capacity fading rate under raised sulfur loading and low electrolyte content. This design strategy promotes the development of practically viable Li–S batteries and sheds lights on the material engineering in related energy storage application. 相似文献
83.
Jongmin Lee Hongji Yoon Kyoung Soon Choi Seungkyu Kim Sehun Seo Jaesun Song Byeong‐Uk Choi Jiseung Ryu Sangwoo Ryu Jihun Oh Cheolho Jeon Sanghan Lee 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(39)
To develop strategies for efficient photo‐electrochemical water‐splitting, it is important to understand the fundamental properties of oxide photoelectrodes by synthesizing and investigating their single‐crystal thin films. However, it is challenging to synthesize high‐quality single‐crystal thin films from copper‐based oxide photoelectrodes due to the occurrence of significant defects such as copper or oxygen vacancies and grains. Here, the CuBi2O4 (CBO) single‐crystal thin film photocathode is achieved using a NiO template layer grown on single‐crystal SrTiO3 (STO) (001) substrate via pulsed laser deposition. The NiO template layer plays a role as a buffer layer of large lattice mismatch between CBO and STO (001) substrate through domain‐matching epitaxy, and forms a type‐II band alignment with CBO, which prohibits the transfer of photogenerated electrons toward bottom electrode. The photocurrent densities of the CBO single‐crystal thin film photocathode demonstrate ?0.4 and ?0.7 mA cm?2 at even 0 VRHE with no severe dark current under illumination in a 0.1 m potassium phosphate buffer solution without and with H2O2 as an electron scavenger, respectively. The successful synthesis of high‐quality CBO single‐crystal thin film would be a cornerstone for the in‐depth understanding of the fundamental properties of CBO toward efficient photo‐electrochemical water‐splitting. 相似文献
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《Ceramics International》2020,46(9):13125-13132
It is of great significance to develop highly active and cost-effective electrocatalysts for the oxygen evolution reaction and hydrogen evolution reaction in alkaline solution. Herein, we report an interface engineering strategy to fabricate 3D hierarchical CuCo2O4@CuCo2S4 heterostructure catalysts with efficient synergistic effects for water splitting. Owing to the special nano-architectures with abundant active interfaces, the as-prepared CuCo2O4@CuCo2S4 catalysts exhibit superior electrochemical activity and prominent electrochemical stability, with a small overpotential of 240 and 101 mV for oxygen and hydrogen evolution reactions to deliver a current density of 10 mA cm−2, respectively. Remarkably, the CuCo2O4@CuCo2S4 materials directly applied as both anode and cathode electrode demonstrate excellent water splitting performance, achieving 10 mA cm−2 at a low cell voltage of only 1.53 V, outperforming the integrated state-of-the-art RuO2||Pt/C couple (1.56 V). Moreover, density functional theory calculations suggest that the excellent overall water splitting property of CuCo2O4@CuCo2S4 is attributed to a large amount of hierarchical hetero-interfaces, giving rise to effective adsorption and cleavage of H2O molecules on the catalyst surface. This work represents a general strategy to exploit efficient and stable hybrid electrocatalysts for renewable energy applications by rational catalyst interface engineering. 相似文献
86.
The solvent-dependent polymorphism of the active pharmaceutical ingredient (API) carbamazepine is interpreted from calculations of the solid-state and API-solvent intermolecular interactions. These simulations suggested that apolar solute-solute interactions could be disrupted by apolar solvents. In contrast, the polar solute-solute interactions were found to be easily disrupted by polar and protic solvents. This is consistent with experimental observations that the crystallization of the metastable form II is more dominant in apolar solvents. The Mercury program remains the gold standard in terms of usability; however, further expansion into more complex simulation techniques could make this package of even greater use in pharmaceutical manufacturing workflows. 相似文献
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目前工程社会学在我国正逐渐兴起,出现了"工程共同体论"、"社会评价论"和"建设工程系统论"三种不同研究范式,各学者对系统的工程社会学体系莫衷一是。本文首先批判性梳理了上述三种范式,指出其对于工程社会学建构的作用和意义;其次,借鉴英国科学社会学家约翰·齐曼对科学社会学知识的类型划分,将工程社会学体系划分为"内部工程社会学"和"外部工程社会学",并提出"工程域"和"工程社区"两个概念,它们是工程社会学的基本范畴,也分别是内部工程社会学和外部工程社会学的核心概念;最后,展望工程社会学发展前景,指出工程社会学必将成为社会学"学术大家庭"中的重要一员。 相似文献